Bhati, N and Sarma, K and Goswami, A
(2008)
Alcohol oxidation in ionic liquid with USP and recyclable amberlite IR-120 acidic resin : a green approach.
Chemistry Letter, 37 (5).
pp. 496-497.
Abstract
Amberlite IR-120 acidic resin, an age old polymer matrix,
plays a significant role as catalyst in the oxidation of aromatic
alcohols with urea 13hydrogen peroxide in ionic liquid at 70 �C
to disproportionate into phenols and carbonyl compounds in
30 1360 min following two pathways. Under similar condition
tertiary aromatic alcohol gave exclusively monohydroxyphenol
accompanied by acetone. However, aliphatic and alicyclic
alcohols yielded carbonyl compounds in moderate to good yields
in 1 135 h.
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