Sharma, B J and Dutta, D K
(2009)
Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building
Block of a Nanoporous Supramolecular Assembly.
Crystal Growth and Design, 9 (4).
pp. 1643-1645.
Abstract
The dimeric units [RhCl2(Hhmp)(hmp)]2, where Hhmp and hmp are 2-(hydroxymethyl)pyridine and anionic deprotonated
ligand, respectively, is formed by strong hydrogen bonding interactions between pairs of Hhmp and hmp ligands that act as building blocks
and self-assemble remarkably through aromatic π-π and CH/-π interactions to generate a nanoporous supramolecular structure exhibiting
permanent porosity and selective adsorption properties.
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