SARMA , KULADIP and BHATI , NISHI and BORTHAKUR , N and GOSWAMI , A
(2007)
A novel method for the synthesis of chiral epoxides from styrene derivatives using chiral acids in presence of Pseudomonas lipase G6 [PSL G6] and hydrogen peroxide.
Tetrahedron, , 63 (36).
pp. 8735-8741.
Abstract
hiralepoxidationofstyreneanditsderivativeswascarriedoutusingseriesofchiralacidsandureahydrogenperoxide(UHP)or
aqueoushydrogenperoxide(50%)intwophasesunderthecatalyticinfluenceofimmobilizedPseudomonaslipaseG6[PSLG6]at25–55 C.
A moderate to good yield and enantioselectivities of chiral epoxides were obtained.
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