GOSWAMI , R L and BOSC , F and COT , D and A EL , MANSOURI and LOPEZ, M and MORATO , F and AYRAL , A
(2004)
Sol-Gel derived nanocomposites and nanoporous oxide powders and related coatings for the reversible chemisorption of hydrogen sulfide.
J Sol-Gel Science & Technology, 29.
pp. 97-105.
Abstract
t. Two types of nanocomposites and nanoporous powders and related coatings were prepared by the
sol-gel route. These silica-based materials contain dispersed reactive oxides, ZnO and ZnCr2O4, respectively. ExperimentsevidencedtheirabilityofreversiblechemisorptionofH2SasZnS.Theirattractiveporouscharacteristics
(smallporesize
∼2–2.5nm,highspecificsurfacearea∼900–1100m2·g−1,highporosity∼50–60%)arenotsignificantlymodifiedduringthesuccessivetreatmentsofH2Schemisorptionandoxideregeneration.Thesepreliminary
results encourage to pursue this study which aims at the preparation of nanofilters for the desulfurization of gas
mixtures.
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