BORUAH , M and KONWAR , D (2002) AlCl3,6H2O/KI/H2O/CH3CN : a new alternate system for dehydration of oximes and amides in hydrated media. J Organic Chemistry, , 67. pp. 7138-7139.

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Dehydration of oximes and amides to nitriles was carried out using the AlCl3â6H2O/KI/H2O/CH3CN system. It produced isoquinoline derivatives 8a-c (Bischler Naperialski reaction) when reacted with amides 7a-c in hydrated media. Also, the keto oximes produced anilides (Beckmann rearrangement) with the system under the same reaction conditions.

Item Type: Article
Subjects: Chemistry > Organic Chemistry
Depositing User: Dr. PK Barooah
Date Deposited: 09 Jan 2012 09:07
Last Modified: 09 Jan 2012 09:09

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