BORUAH , M and KONWAR , D
(2002)
AlCl3,6H2O/KI/H2O/CH3CN : a new alternate system for dehydration of oximes and amides in hydrated media.
J Organic Chemistry, , 67.
pp. 7138-7139.
Abstract
Dehydration of oximes and amides to nitriles was
carried out using the AlCl3â6H2O/KI/H2O/CH3CN system. It
produced isoquinoline derivatives 8a-c (Bischler Naperialski
reaction) when reacted with amides 7a-c in hydrated
media. Also, the keto oximes produced anilides (Beckmann
rearrangement) with the system under the same reaction
conditions.
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